1.
1) СH4 + Br2 =(уф.)=> CH3Br + HBr
2) 2CH3Br + 2Na => СH3-CH3 + 2NaBr
3) CH3-CH3 =(Pt,t)=> CH2=CH2 + H2
4) CH2=CH2 =(Pt,t)=> CH≡CH + H2
5) 3CH≡CH =(Caкт, 600 °С)=> C6H6
6) C6H6 + HNO3 =(H2SO4)=> C6H5NO2 + H2O
2.
1) 2CH4 =(1500 °C)=> CH≡CH + 3H2
2) CH≡CH + H2O =(Hg²⁺)=> СH3-CHO
3) CH3-CHO + H2 =(Ni,t)=> CH3-CH2OH
4) 5CH3-CH2OH + 4KMnO4 + 6H2SO4 = 5CH3COOH + 2K2SO4 + 2MnSO4 + 11H2O
5) CH3COOH + C3H7OH =(H2SO4)=> CH3COOC3H7 + H2O
3.
1) 3CH≡CH =(Сакт, 600 °С)=> C6H6
2) C6H6 + HNO3 =(H2SO4)=> C6H5NO2 + H2O
3) C6H5NO2 + 3H2 =(Ni,t)=> C6H5NH2 + 2H2O
4) CH≡CH + H2O =(Hg²⁺)=> CH3-CHO
5) CH3-CHO + Ag2O =(NH3,t)=> CH3COOH + 2Ag
6) CH3COOH + Cl2 =(Pкр)=> CH2Cl-COOH + HCl
7) СH2Cl-COOH + NH3 => NH2-CH2-COOH + HCl
Объяснение:
1.
1) СH4 + Br2 =(уф.)=> CH3Br + HBr
2) 2CH3Br + 2Na => СH3-CH3 + 2NaBr
3) CH3-CH3 =(Pt,t)=> CH2=CH2 + H2
4) CH2=CH2 =(Pt,t)=> CH≡CH + H2
5) 3CH≡CH =(Caкт, 600 °С)=> C6H6
6) C6H6 + HNO3 =(H2SO4)=> C6H5NO2 + H2O
2.
1) 2CH4 =(1500 °C)=> CH≡CH + 3H2
2) CH≡CH + H2O =(Hg²⁺)=> СH3-CHO
3) CH3-CHO + H2 =(Ni,t)=> CH3-CH2OH
4) 5CH3-CH2OH + 4KMnO4 + 6H2SO4 = 5CH3COOH + 2K2SO4 + 2MnSO4 + 11H2O
5) CH3COOH + C3H7OH =(H2SO4)=> CH3COOC3H7 + H2O
3.
1) 3CH≡CH =(Сакт, 600 °С)=> C6H6
2) C6H6 + HNO3 =(H2SO4)=> C6H5NO2 + H2O
3) C6H5NO2 + 3H2 =(Ni,t)=> C6H5NH2 + 2H2O
4) CH≡CH + H2O =(Hg²⁺)=> CH3-CHO
5) CH3-CHO + Ag2O =(NH3,t)=> CH3COOH + 2Ag
6) CH3COOH + Cl2 =(Pкр)=> CH2Cl-COOH + HCl
7) СH2Cl-COOH + NH3 => NH2-CH2-COOH + HCl
Объяснение: